The electronic configuration of these elements are as given below:
Electronic configuration of Li is 1s22s1
That of Si is 1s22s22p63s23p2
Electronic configuration for He = 1s2
Electronic Configuration of Na is 1s22s22p63s1
That of P is 1s22s22p63s23p3
From this it is seen that elements Na, Si and P have the same value as the principle quantum number of the outermost shell.